Passivation of stainless steel astm a967, qqp35, ams 2700. The vgb guideline preservation of power plants is a summary of existing and revised literature on preservation methods according to the stateoftheart. Steam boiler boilouts passivation boiler and pressure. Passivation is the process of treating the metal with acids in order to remove the free iron from the surface of the metal and coat it with this corrosionpreventing oxide layer. Edta cleaning processalkali flushing procedure alkali flushing alkali solution made by adding tsp0.
Refer to section 15185 for a complete list of sections related to chemical cleaning and treatment of mechanical systems. The manufacturing process of the boilers is clearly a dirty process, and there is a large risk that the boilers will be contaminated with millscale,oils, or slag from the manufacture of the boiler. It is a systematic procedure used after completion of erection in making the boiler and its auxiliaries available for safe, smooth and reliable operation. Sh outlet pressure sh outlet temperature feed water temperature at eco inlet maximum continuous rating 155 kgcm2 540 0 c 247 0 c 865 th water holding capacity. One can reference industry standards astm a380 and astm a967 for guidance on the procedure to be followed. New developments in passivation technology have proceeded in two different areas. Why recommend ammoniated citric acid for the chemical.
Boiler water treatment association of water technologies. Grinding to remove weld spatter and smooth out scratches. In the case of hcl, passivation is preceded by rinses and neutralization of any remaining acid in the boiler. The formation of this protective layer is called passivation. Experimental procedure chemicals used for cleaning operation were hydrazine hydrate 64 % russia ori gi n, sulphuric. The pitting corrosion leads to boiler tube failures and might damage. Proper commissioning and initial startup procedures extend. Such coatings must be removed since they reduce the heat transfer. Cn102586772b passivation process after chemical cleaning. Boilout procedure steam boilers preface the internal surfaces of a newly installed boiler may be contaminated with oil, grease or other protective coatings used in the manufacturing process. However, the chemical passivation forms a good substrate for conversion systems such as chromating and phosphating processes. How do i passivate stainless steel parts after machining operations.
The process comprises preparing a passivation solution, and adding the passivation solution after the cleaning of the boiler is passed, and circulating at 1535 deg c for 812 hours, wherein the passivation solution comprises methanol, sodium hydrogen sulfate, hydrazine, trialkyl ammonium chloride, ammonia and water, the contents of the above components in per liter of the passivation solution are as follows. Carbonate and bicarbonate alkalinities can combine with calcium and. The ferric iron content of the cleaning solution shall be monitored to avoid the attack on the metal. In order to carry out a thorough passivation, the boiler should be chemically clean. I want to know in boiler passination and boil out the.
Avestapolarit welding pickling handbook handbook for the pickling and cleaning of stainless steel. Boiler boil out and passivation posted in refining, hydrocarbons, oil, and gas. Patchy, uneven pickled surfaces can result if surfaces are not clean before the acid treatment. Is there any hplc passivation procedure available for. Evaluation of boiler chemical cleaning techniques inis. Ss passivating chemicals are domestically available, and these are used by circulating within the ss pipelines and boiler. When boiler goes back on line, check areas for steam. Chemical clean, passivation new boiler cleaning pipe work.
The operational and safety aspects of chemical cleaning of. This will extend the life of the vessel by protecting it from corrosion. Banes, astro pak corporation to insure having the maximum corrosion resistance that austenitic stainless steel has to offer, the stainless steel surface must be in a passive state. Use of ammoniated citric acid for the chemical cleaning of high pressure boilers. Mud or bottom blowdown is usually a manual procedure done for a few seconds on intervals. Steam blowing of supercritical thermal power plant 2x800. While the inertness of surfaces in the flow path is very good and the level of elution of metal ions from agilent hplc systems is. This is done by adding a chemical that removes free iron and allows chromium oxide to form. Boiler boil out and passivation refining, hydrocarbons. Boiler inspections are dirty, usually hot and wet, confining and always a humbling experience, but they are absolutely essential. Learn more about industrial boiler water treatment, causes and types of boiler. Stainless steel is able to resist corrosion thanks to a passive chromium oxide layer that forms on its surface. If steam is not going to certain areas check steam lines for water and drain.
Boiler water treatment principles and practice, volume 1. Chemical cleaning is a multiple stage process that seeks to remove all the existing scale from the boiler internals, leaving a clean, passivated waterside system. Mechanical cleaning and water flushing can remove loose scale and other debris from the boiler through wiping, brushing, blowing, and friction method. The cleaning mechanism and passivation on clean surface of tubes by circulation of 500 mg l1. Pickling and passivating stainless steel light scaling left on weld caps and heat tint on the surrounding parent tube surfaces can usually be removed by acid pickling. Proper boiler water treatment is the key to a successful steam boiler startup and.
Boiler water treatment introduction a boiler is a closed vessel in which water under pressure is transformed into steam by the application of heat. The boiler is lighted up and pressured is raised to 40 kg per cm2 the sample is to be tested for hydrazine concentration and should not be less than 25 ppm after 24 hours fire should be killed and boxed up open super heater vent at 90c and boiler is drained, the second stage passivation marks completion of chemical cleaning 8 passivation. Sufficient disodium phosphate must be available to combine with all of the. Why passivate stainless steel and what happens if you dont by. This passive layer gets damaged through heat or chemical damage due to high humidity levels. A thorough rinsing with fresh water, preferably using. Tanis, procedures of industrial water treatment, ltan inc.
Proper commissioning and initial startup procedures extend boiler life. Boiler alkali boil out is carried out to remove material such as lubricants, oil and rust. Steam boiler alkali boil out procedure boilersinfo. Abrasion or excessive heat caused by welding will destroy this protective layer and expose the metal to corrosion. A twostep procedure can provide the best possible corrosion resistance. Nalco 77262 is designed to assure a high level of cleanliness in the boiler system, especially on the heat transfer surfaces, together with a complete corrosion inhibiting action. Standard practice for cleaning, descaling, and passivation. Fill the boiler with demiwater and supply steam until temperatures reaches to. Jim robinson senior boiler consultant, trevose, pa ed baumgartner senior project sales, spokane, wa.
These are common questions asked by machining shops and manufacturers of various part materials. Economizer corrosion control involves procedures similar to those employed for. A newly constructed boiler will be contaminated by particulate debris, oils and greases, and rust. The initial cleaning of a new boiler or pipework is critical to its operational success. Why passivate stainless steel and what happens if you dont. Passivation of mild steel boiler tubes august 22, 2016. After passivation, various tests can be performed to verify whether passivation has been properly performed. Standard practice for cleaning, descaling, and passivation of stainless steel parts, equipment, and systems1 this standard is issued under the. Unless otherwise specified, passivation in the present context is the chemical treatment of a stainless steel with a mild oxidant so as to remove free iron from the surface and speed up the process of forming a protectivepassive layer. Acid cleaning operation for a natural circulation high pressure drum boiler unit of a thermal power station. Passivation is the process of forming a passive layer of chromium oxide on the surface of stainless steel to protect it from corrosion.
Index foreword 1 1 stainless steel and the need for cleaning 2 1. A number in parentheses indicates the year of last. During fabrication and erection of the pressure parts, some amount of oil and lubricants can also. Boiler passivation wholesale, passivation suppliers alibaba. The total iron content shall not exceed 150 gm as fe in 1 liters of the cleaning solution. Nalco 77262 can be applied in low pressure boiler systems without deaerator and on softened feedwater makeup with a total feedwater. Hplc passivation procedure for sensitive applications like e. Part i deals with the watersteamside preservation of power plants and power plant components, whereas part ii concentrates on the fluegas. A discussion started in 2001 but continuing through 2019. Passivation is designed to maximize the inherent corrosion resistance of stainless steel parts after machining. Boilout procedure watertube steam boilers preface the internal surfaces of a newly installed boiler may be contaminated with oil, grease or other protective coatings used in the manufacturing process.
Acid cleaning operation for a natural circulation high. Before a boiler is put into service, it is customary to follow a precommissional chemical cleaning procedure. In the case of edta, passivation occurs after cooling the boiler to 160f and after the. Added costs grow rapidly with no or poorly applied chemical cleanings. The first of these new developments is the improvement in chemistry for the removal of surface contaminants and the second is the employment of advanced instrumental techniques to measure the passive layer.
Reducing corrosion and potential boiler failure with. Back to startup back to onsite services chemical clean and passivation. On section 3 boiler fouling build up due to metal load will be described and analyzed. Alternatively, when it concerns the water side of a system, the passive film formed will be a good basis for the boiler water treatment programme. During manufacturing seamless steel tubes, mill scales are bound to be formed, and some of these can remain inside. The limits for iron and ferric iron shall not exceed 0.
Pdf analysis of the acid passivation of stainless steel. Passivation of stainless steel is a process that removes free iron from the surface of a stainless component and at the same time promotes the formation of a thin, dense oxide protective barrier. Fill the boiler completely to the stop valve with softened, and if possible deaerated, water that is treated with catalyzed sodium sulphite and caustic soda. The reference for passivation of stainless steel is astm a967. Postfabrication cleaning is the process of cleaning after fabrication. Pdf preoperational cleaning requirements for hrsg units. Passivation of stainless steel vessels for boilers is a recommended practice.
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